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Platinum(II)-mediated dehydrosulfurization and oxidative carbon-carbon coupling in the gas-phase decomposition of thioethers
- 1.0326524 - ÚOCHB 2010 RIV NL eng J - Journal Article
Butschke, B. - Schlangen, M. - Schröder, Detlef - Schwarz, H.
Platinum(II)-mediated dehydrosulfurization and oxidative carbon-carbon coupling in the gas-phase decomposition of thioethers.
International Journal of Mass Spectrometry. Roč. 283, č. 1 (2009), s. 3-8. ISSN 1387-3806. E-ISSN 1873-2798
Institutional research plan: CEZ:AV0Z40550506
Keywords : bond activation * bond formation * platinum chemistry * reaction mechanisms * thio ethers
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 2.117, year: 2009
The ion/molecule reaction of [Pt(bipy – H)]+ (bipy = 2,2'-bipyridine) with dimethyl sulfide leads to the loss of ethene in the main reaction channel. This process corresponds to a formal dehydrosulfurization (DHS) accompanied by oxidative C–C coupling.
Permanent Link: http://hdl.handle.net/11104/0173605
Number of the records: 1