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Nucleophilic difluoromethylenation of aldehydes and ketones using diethyl difluoro(trimethylsilyl)methylphosphonate

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    0326484 - ÚOCHB 2010 RIV CH eng J - Journal Article
    Alexandrova, Anastasia - Beier, Petr
    Nucleophilic difluoromethylenation of aldehydes and ketones using diethyl difluoro(trimethylsilyl)methylphosphonate.
    Journal of Fluorine Chemistry. Roč. 130, č. 5 (2009), s. 493-500. ISSN 0022-1139. E-ISSN 1873-3328
    R&D Projects: GA ČR GP203/08/P310
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : phosphonates * phosphates * nucleophilic additions * difluoromethylene
    Subject RIV: CC - Organic Chemistry
    Impact factor: 1.730, year: 2009

    Phosphates of syn and anti 2,2-difluoro-1,3-diols can be conveniently prepared from aldehydes and ketones under mild conditions using diethyl difluoro(trimethylsilyl)methylphosphonate.
    Permanent Link: http://hdl.handle.net/11104/0173577

     
     
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