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An efficient and highly selective synthesis of (Z)-fluoroenol phosphates from hydroxy difluorophosphonates

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    0322902 - ÚOCHB 2009 RIV DE eng J - Journal Article
    Beier, Petr - Pohl, Radek - Alexandrova, Anastasia
    An efficient and highly selective synthesis of (Z)-fluoroenol phosphates from hydroxy difluorophosphonates.
    [Efektivní a vysoce selektivní syntéza (Z)-fluoroenol fosfátů z hydroxy difluorofosfonátů.]
    Synthesis. -, č. 6 (2009), s. 957-962. ISSN 0039-7881. E-ISSN 1437-210X
    R&D Projects: GA ČR GP203/08/P310
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : phosphonates * phosphates * rearrangements * eliminations * enols
    Subject RIV: CC - Organic Chemistry
    Impact factor: 2.572, year: 2009

    Substituted 2-aryl-2-hydroxy-1,1-difluorophosphonates undergo a reaction with potassium tert-butoxide to provide selectively (Z)-2-fluoro-1-arylvinyl phosphates in high yields.

    Substituované 2-aryl-2-hydroxy-1,1-difluorofosfonáty reagují s tert-butylátem draselným za vzniku (Z)-2-fluoro-1-arylvinyl fosfátů ve vysokých výtěžcích.
    Permanent Link: http://hdl.handle.net/11104/0171035

     
     
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