Kinetic Investigation of the Electrochemical Oxidation of Bis(benzene)chromium(0) in Diethyl ketone / N,N-Dimethylformamide

0318218 - ÚOCHB 2009 RIV US eng J - Journal Article
Tsierkezos, Nikos
Kinetic Investigation of the Electrochemical Oxidation of Bis(benzene)chromium(0) in Diethyl ketone / N,N-Dimethylformamide.
[Výzkum kinetiky elektrochemické oxidace Bis(benzen)chromu(0) v diethylketonu / N,N-dimethylformamidu (mravenčanu).]
Journal of Solution Chemistry. Roč. 37, č. 10 (2008), s. 1437-1448. ISSN 0095-9782. E-ISSN 1572-8927
Institutional research plan: CEZ:AV0Z40550506
Keywords : bis(benzene)chromium(0) * cyclic voltammetry * diethyl ketone * half-wawe potential * N,N-dimethylformamide
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 1.241, year: 2008

Cyclic voltammetry was applied for the investigation of the electrochemical oxidation of bis(benzene)chromium(0), (C6H6)2Cr to bis(benzene)chromium(I), (C6H6)2Cr+ in diethyl ketone (DEK), N,N-dimethylformamide (DMF), and DEK / DMF binary mixtures at T = 298.15 K.

Pro výzkum elektrochemické oxidace byla využita cyklická voltametrie bis(benzen)chromu(0), (C6H6)2Cr, oxidovaného na bis(benzen)chrom(I), (C6H6)2Cr+ v prostředí diethylketonu (DEK), N,N-dimethylformamidu (DMF) a směsi DEK/DMF při teplotě T = 298.15 K.
Permanent Link: http://hdl.handle.net/11104/0167689