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Organized Mesoporous Alumina: Synthesis, Structure and Potential in Catalysis

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    0181820 - UFCH-W 20030262 RIV NL eng J - Journal Article
    Čejka, Jiří
    Organized Mesoporous Alumina: Synthesis, Structure and Potential in Catalysis.
    Applied Catalysis A - General. Roč. 254, - (2003), s. 327-338. ISSN 0926-860X. E-ISSN 1873-3875
    R&D Projects: GA AV ČR IAA4040001; GA ČR GA104/02/0571; GA MŠMT ME 404
    Institutional research plan: CEZ:AV0Z4040901
    Keywords : organized mesoporous alumina * mesoporous molecular sieves * synthesis
    Subject RIV: CF - Physical ; Theoretical Chemistry
    Impact factor: 2.825, year: 2003

    Organized mesoporous alumina represents a very interesting molecular sieve exhibiting a narrow pore size distribution with higher surface areas compared to conventional aluminas, used as a support for catalytically active species in numerous large-scale industrial processes. This review encompasses various synthesis approaches to organized mesoporous aluminas, description of their structures and properties, and characterization by various experimental techniques. The potential of the mesoporous alumina with respect to use in catalysis is also outlined. Surface areas up to 800 m2/g and pore sizes ranging from 2.0 to more than 10 nm are characteristic for organized mesoporous aluminas prepared by neutral, anionic and cationic synthesis routes. Although utilization of mesoporous aluminas as a support in catalysis has not been reported frequently, they have a certain potential in hydrodesulfurization and metathesis reactions.
    Permanent Link: http://hdl.handle.net/11104/0001940

     
     

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