0181313 - UFCH-W 20010237 RIV CH eng J - Journal Article
Kaim, W. - Sixt, T. - Weber, M. - Fiedler, Jan
Iron(II) versus Osmium(II) Oxidation in 1,1'-Bis(diorganophosphino)Ferrocene-Osmium(II) Complexes.
Journal of Organometallic Chemistry. 637-639, - (2001), s. 167-171. ISSN 0022-328X. E-ISSN 1872-8561
R&D Projects: GA MŠMT OC D15.10
Institutional research plan: CEZ:AV0Z4040901
Keywords : electrochemistry * EPR spectroscopy * osmium complexes
Subject RIV: CG - Electrochemistry
Impact factor: 1.803, year: 2001

The complexes of Os with p-cymene, chloride and bis(diphenylphosphino)- or bis(diethylphosphino)- or (diisopropylphosphino)ferrocene were synthesized and characterized by NMR, X-ray and spectroelectrochemically. Osmium(II)- ferrocenium species is formed on reversible one-electron oxidation. The second oxidation and the reduction are electrochemically irreversible.
Permanent Link: http://hdl.handle.net/11104/0077895