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Li Insertion Into Li-Ti-O Spinels: Voltammetric and Electrochemical Impedance Spectroscopy Study

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    0181255 - UFCH-W 20010171 RIV US eng J - Journal Article
    Krtil, Petr - Fattakhova, Dina
    Li Insertion Into Li-Ti-O Spinels: Voltammetric and Electrochemical Impedance Spectroscopy Study.
    Journal of the Electrochemical Society. Roč. 148, č. 9 (2001), s. A1045-A1050. ISSN 0013-4651. E-ISSN 1945-7111
    R&D Projects: GA ČR GA203/99/0879
    Institutional research plan: CEZ:AV0Z4040901
    Keywords : Li insertion * impedance spectroscopy * Frumkin insertion isotherm
    Subject RIV: CG - Electrochemistry
    Impact factor: 2.033, year: 2001

    The insertion into spinel occurs at potential 300mV more negative to that of insertion into anatase and about 40mV positive to that into rutile. The specific capacity (160mAh/g) is comparable with that of TiO2 polymorphs. Due to the relatively negative potential of the insertion and significantly lower tendency to self-discharge Li-Ti-O spinel is more convenient for use in 2V lithium ion battery than other active physes in the Li-Ti-O system.
    Permanent Link: http://hdl.handle.net/11104/0077838

     
     

Number of the records: 1  

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