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Evaluation of the Standard Ion Transfer Potentials for PVC Plasticized Membranes from Voltammetric Measurements

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    0181102 - UFCH-W 20010004 RIV CH eng J - Journal Article
    Langmaier, Jan - Stejskalová, Květoslava - Samec, Zdeněk
    Evaluation of the Standard Ion Transfer Potentials for PVC Plasticized Membranes from Voltammetric Measurements.
    Journal of the Electroanalytical Chemistry and Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. Roč. 496, č. 1 (2001), s. 143-147. ISSN 0022-0728.
    [Symposium in Kyoto. Kyoto, 02.03.2000]
    R&D Projects: GA AV ČR IAA4040902
    Institutional research plan: CEZ:AV0Z4040901
    Keywords : ion voltammetry * PVC plasticized membrane * standard ion transfer potential
    Subject RIV: CG - Electrochemistry
    Impact factor: 1.960, year: 2001

    Voltammetric measurements were used to investigate the transfer of a series of semi-hydrophobic ions across the interface between an aqueous electrolyte solution and the o-NPOE PVC membrane. Standard ion transfer potentials were evaluated which are comparable with those inferred from measurements at a water/o-NPOE interface. The presence of PVC has a rather small effect on the ion transfer thermodynamics, which is probably due to very weak interactions between PVC and o-NPOE or ions present.
    Permanent Link: http://hdl.handle.net/11104/0077702

     
     

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