Number of the records: 1
Redox Chemistry of[Co.sub.4./sub.(CO).sub.3./sub.(.mu..sub.3./sub.-CO).sub.3./sub.(.mu..sub.3./sub.-C.sub.7./sub.H.sub.7./sub.)(.eta..sup.5./sup.-C.sub.7./sub.H.sub.9./sub.)] - Reversible Carbon-Carbon Coupling versus Metal Cluster Degradation
- 1.0181043 - UFCH-W 20000214 RIV DE eng J - Journal Article
Wadepohl, H. - Gebert, S. - Pritzkow, H. - Osella, D. - Nervi, C. - Fiedler, Jan
Redox Chemistry of[Co4(CO)3(.mu.3-CO)3(.mu.3-C7H7)(.eta.5-C7H9)] - Reversible Carbon-Carbon Coupling versus Metal Cluster Degradation.
European Journal of Inorganic Chemistry. č. 8 (2000), s. 1833-1843. ISSN 1434-1948. E-ISSN 1099-0682
R&D Projects: GA MŠMT OC D15.10
Institutional research plan: CEZ:AV0Z4040901; CEZ:A54/98:Z4-040-9-ii
Subject RIV: CG - Electrochemistry
Impact factor: 2.222, year: 2000
The complex potential current response of [Co4(CO)6(C7H7)(C7H9) is rationalized in terms of the formation of the radical anion as the primary intermediate, which may be reversibly reduced further to give the much more stable dianion.
Permanent Link: http://hdl.handle.net/11104/0077650
Number of the records: 1