0172392 - UEB-Q 20033100 RIV DE eng J - Journal Article
Marek, J. - Kopel, P. - Trávníček, Zdeněk
[N,N'-Bis(3-aminopropyl)ethylenediamine-kappa4N,N',N",N"'](trithiocyanurato-kappa2N,S)zinc(II) ethanol solvate.
Acta Crystallographica Section C-Crystal Structure Communications. Roč. 59, č. 12 (2003), s. 558-560. ISSN 0108-2701. E-ISSN 2053-2296
R&D Projects: GA ČR GA203/00/0152
Institutional research plan: CEZ:AV0Z5038910
Keywords : crystal structure * bidentate ligand * hydrogen bonds
Subject RIV: CE - Biochemistry
Impact factor: 0.828, year: 2003

In the crystal structure of the title compound, [N,N'-bis(3-aminopropyl)ethylenediamine-kappa(4)N,N',N",N"'][1,3,5-triazine-2,4,6(1H,3H,5H)-trithionato(2-)-kappa(2)N,S]zinc(II) ethanol solvate, [Zn(C(8)H(22)N(4))(2)(C(3)HN(3)S(3))].C(2)H(6)O, the Zn(II) atom is octahedrally coordinated by four N atoms [Zn-N = 2.104 (2)-2.203 (2) A] of a tetradentate N-donor N,N'-bis(3-aminopropyl)ethylenediamine (bapen) ligand and by two S and N atoms [Zn-S = 2.5700 (7) A and Zn-N = 2.313 (2) A] of a trithiocyanurate(2-) (ttcH(2-)) dianion bonded as a bidentate ligand in a cis configuration. The crystal structure of the compound is stabilized by a network of hydrogen bonds.
Permanent Link: http://hdl.handle.net/11104/0069431