0162187 - UIACH-O 200022 RIV DE eng J - Journal Article
Horká, Marie - Šlais, Karel
Low-conductivity background electrolytes in capillary zone electrophoresis - myth or reality?
Electrophoresis. Roč. 21, č. 14 (2000), s. 2814-2827. ISSN 0173-0835. E-ISSN 1522-2683
R&D Projects: GA AV ČR IAA4031901; GA AV ČR KSK2055603
Subject RIV: CB - Analytical Chemistry, Separation
Impact factor: 3.385, year: 2000

The parametr named relative velocity slope, SBGE,X, was introduced as a quantity characterising the peak broadening and the asymmetry. SBGE,X vs. analyte ionic mobility diagrams are suitable for the comparison of background electrolytes, BGEs, of different pKas and ionic mobility. It follows from both theoretical predictions of peak symmetry and their experimental verification that the optimum composition of BGEs is determined mostly by the suitable ionic mobility of the coion in dependence on the ionic mobility of the analyte.
Permanent Link: http://hdl.handle.net/11104/0059507