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On the relationship between entropy and enthalpy of grain boundary segregation

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    0133821 - FZU-D 20020101 RIV NL eng J - Journal Article
    Lejček, Pavel - Hofmann, S.
    On the relationship between entropy and enthalpy of grain boundary segregation.
    Interface Science. Roč. 9, - (2002), s. 221-230. ISSN 0927-7056
    R&D Projects: GA ČR GA202/99/1665; GA ČR GA106/99/1178; GA AV ČR IAA1010916; GA MŠMT OC 517.40
    Institutional research plan: CEZ:AV0Z1010914
    Keywords : grain boundaries * segregation * anisotropy * thermodynamics
    Subject RIV: BM - Solid Matter Physics ; Magnetism
    Impact factor: 0.767, year: 2002

    The linear relationship between segregation entropy and enthalpy for all grain boundaries is analyzed from the thermodynamic point of view. It is shown that this linear relationship is a consequence of an interconnection of the value of segregation enthalpy and entropy for different types of grain boundaries.
    Permanent Link: http://hdl.handle.net/11104/0031776

     
     

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