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Role of hydration in the phase transition of polypeptides investigated by NMR and Raman spectroscopy

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    0101285 - UMCH-V 20043005 RIV DE eng J - Journal Article
    Dybal, Jiří - Schmidt, Pavel - Kříž, Jaroslav - Kurková, Dana - Rodriguez-Cabello, J. C. - Alonso, M.
    Role of hydration in the phase transition of polypeptides investigated by NMR and Raman spectroscopy.
    [Role hydratace ve fázovém přechodu polypeptidů zkoumaná pomocí NMR a Ramanovy spektroskopie.]
    Macromolecular Symposia. Roč. 205, - (2004), s. 143-150. ISSN 1022-1360
    R&D Projects: GA AV ČR IAA4050208
    Institutional research plan: CEZ:AV0Z4050913
    Keywords : NMR * quantum chemistry * Raman spectroscopy
    Subject RIV: CD - Macromolecular Chemistry
    Impact factor: 0.691, year: 2004

    NMR, Raman spectroscopy and ab initio quantum-chemical calculations have been employed to investigate the role of the hydration water in the inverse temperature transition of elastin-derived biopolymers represented by poly(Gly-Val-Gly-Val-Pro) and poly(Ala-Val-Gly-Val-Pro).

    NMR, Ramanova spektroskopie a kvantově chemické výpočty byly použity k objasnění role hydratace v inverzním teplotním přechodu biopolymerů odvozených od elastinu, zastoupených poly(Gly-Val-Gly-Val-Pro) a poly(Ala-Val-Gly-Val-Pro).
    Permanent Link: http://hdl.handle.net/11104/0008719

     
     
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