Macropolyhedral boron-containing cluster chemistry. Cluster opening and B-frame rearrangement in the reaction of B16H20 with [{(IrCl2(eta(5)-C5Me5)}(2)]. Synchrotron X-ray structures of [(eta(5)-C5Me5)(2)Ir2B16H17Cl] and [(eta(5)-C5Me5)(2)Ir2B16H15Cl]

0050894 - ÚACH 2007 RIV GB eng J - Journal Article
Carr, MJ. - Perera, SD. - Jelínek, Tomáš - Kilner, C. A. - Clegg, W. - Štíbr, Bohumil - Kennedy, J.D.
Macropolyhedral boron-containing cluster chemistry. Cluster opening and B-frame rearrangement in the reaction of B16H20 with [{(IrCl2(eta(5)-C5Me5)}(2)]. Synchrotron X-ray structures of [(eta(5)-C5Me5)(2)Ir2B16H17Cl] and [(eta(5)-C5Me5)(2)Ir2B16H15Cl].
[Macropolyedrická borová klastrová chemie. Otevření klastru a přesmyk B-skeletu při reakci B16H20 s [{(IrCl2(eta(5)-C5Me5)}(2)].Synchrotronové rentgenové struktury [(eta(5)-C5Me5)(2)Ir2B16H17Cl] a [(eta(5)-C5Me5)(2)Ir2B16H15Cl].]
Dalton Transactions. Roč. 44, - (2006), s. 5221-5224. ISSN 1477-9226. E-ISSN 1477-9234
R&D Projects: GA AV ČR(CZ) IAA400320601; GA ČR GA203/05/2646
Grant - others:EPSRC(GB) J/56929; EPSRC(GB) GR/L/49505; EPSRC(GB) R/61949
Institutional research plan: CEZ:AV0Z40320502
Keywords : intercluster bonding intimagy * matallaborane clusters * crystal-structures
Subject RIV: CA - Inorganic Chemistry
Impact factor: 3.012, year: 2006

Products from the reaction of + nido ten- vertex : nido eight-vertex, B16H20 1 with [{( IrCl2(eta(5)- C5Me5)} (2)] and tmnd show unanticipated rearrangement of the starting {B-16} skeleton, as exhibited by + nido ten- vertex : nido ten- vertex, [(eta(5)- C5Me5) (2) Ir2B16H17Cl] 2 which has a {B-2} edge conjunction and by + nido ten- vertex : nido eleven- vertex, [(eta(5)- C5Me5) 2Ir2B16H15Cl] 3 which has a {B-3} face conjunction.

Macropolyedrická borová klastrová chemie. Otevření klastru a přesmyk B-skeletu při reakci B16H20 s [{(IrCl2(eta(5)-C5Me5)}(2)]. Synchrotronové rentgenové struktury [(eta(5)-C5Me5)(2)Ir2B16H17Cl] a [(eta(5)- C5Me5)(2)Ir2B16H15Cl].
Permanent Link: http://hdl.handle.net/11104/0140927