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General approach to neolignan-core of the boehmenan natural product family
- 1.0489372 - ÚEB 2019 RIV AT eng J - Journal Article
Barbuščáková, Z. - Kozubíková, H. - Zálešák, B. - Doležal, Karel - Pospíšil, Jiří
General approach to neolignan-core of the boehmenan natural product family.
Monatshefte fur Chemie. Roč. 149, č. 4 (2018), s. 737-748. ISSN 0026-9247. E-ISSN 1434-4475
R&D Projects: GA MŠMT(CZ) LO1204
Institutional support: RVO:61389030
Keywords : Biomimetic synthesis * Enzymes * Natural products * Oxidative coupling
OECD category: Biochemistry and molecular biology
Impact factor: 1.501, year: 2018
A novel approach to the neolignan-core skeletons of boehmenan natural products and to dehydrodiconiferyl alcohol glucosides based on the Fe(III)-promoted oxidative coupling has been achieved. Obtained common intermediates were further selectively modified to yield the basic molecular core possessing three orthogonally protected alkoxy functionalities available for further selective modifications.
Permanent Link: http://hdl.handle.net/11104/0283796
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