Use of Heterogenized Metal Complexes in Hydrogenation Reactions: Comparison of Hydrogenation and CTH Reactions.

0457734 - ÚCHP 2016 RIV NL eng J - Journal Article
Bata, P. - Zsigmond, A. - Gyémánt, M. - Czeglédi, A. - Klusoň, Petr
Use of Heterogenized Metal Complexes in Hydrogenation Reactions: Comparison of Hydrogenation and CTH Reactions.
Research on Chemical Intermediates. Roč. 41, č. 12 (2015), s. 9281-9294. ISSN 0922-6168. E-ISSN 1568-5675.
[Pannonian Symposium on Catalysis /12./. Castle Trest, 16.09.2014-20.09.2014]
Institutional support: RVO:67985858
Keywords : catalytic transfer hydrogenation * iron-phthalocyanine catalyst * chemoselectivity
Subject RIV: CI - Industrial Chemistry, Chemical Engineering
Impact factor: 1.833, year: 2015

In the fine chemicals industry the preference for heterogeneous over homogeneous catalysts is well known. However, the activity and selectivity of heterogeneous metal complexes are usually better than those of their homogeneous counterparts. There has, consequently, been an increasing demand for heterogenized metal complexes which combine the advantages of both types of catalyst. In the production of fine chemicals, selectivity is probably its most important property of a catalyst. Chemoselectivity, regioselectivity, and enantioselectivity are very important in the synthesis of fine chemicals. Several examples of hydrogenation with heterogenized metal complexes have been studied, with emphasis on selectivity. Catalytic transfer hydrogenation is also discussed, as an alternative to classical hydrogenation.
Permanent Link: http://hdl.handle.net/11104/0258095