Synthesis of Substituted Titanocene Dichloride Derivatives by Hydrosilylation

0429971 - ÚCHP 2015 RIV CH eng J - Journal Article
Strašák, Tomáš - Karban, Jindřich - Červenková Šťastná, Lucie - Maixnerová, Lucie - Březinová, Anna - Bernard, Martin - Fajgar, Radek
Synthesis of Substituted Titanocene Dichloride Derivatives by Hydrosilylation.
Journal of Organometallic Chemistry. Roč. 768, OCT 1 (2014), s. 115-120. ISSN 0022-328X. E-ISSN 1872-8561
Institutional support: RVO:67985858 ; RVO:61388963
Keywords : titanocene dichloride * hydrosilylation * carbohydrates
Subject RIV: CC - Organic Chemistry
Impact factor: 2.173, year: 2014

Substituted titanocene complexes have been prepared by hydrosilylation of organic substrates containing a terminal double bond by cyclopentadienyl complexes of titanium bearing a Si–H functional group. This new synthetic protocol is demonstrated by synthesis of mono-, bi- and trihomonuclear complexes. The structures of prepared compounds have been characterized by standard methods (NMR, IR, and HRMS).
Permanent Link: http://hdl.handle.net/11104/0236105