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Theoretical Background for Predicting the Properties of Petroleum Fluids via Group Contribution Methods
- 1.0383287 - ÚCHP 2013 RIV NL eng J - Journal Article
Bogdanić, Grozdana - Pavlíček, Jan - Wichterle, Ivan
Theoretical Background for Predicting the Properties of Petroleum Fluids via Group Contribution Methods.
Procedia Engineering. Roč. 42, SI (2012), s. 1873-1878. E-ISSN 1877-7058.
[International Congress of Chemical and Process Engineering CHISA 2012 and 15th Conference PRES 2012 /20./. Prague, 25.08.2012-29.08.2012]
Institutional support: RVO:67985858
Keywords : petroleum fluids * prediction * physico-chemical properties
Subject RIV: CF - Physical ; Theoretical Chemistry
The major problem encountered in the petroleum industry lies in the proper thermodynamic representation of rather complex fluids. In this work, the UNIFAC group contribution method for predicting the properties of such fluids has been exploited as a basis for their description in terms of model compounds. Standard thermodynamic procedures are used to estimate the critical properties, acentric factors, and molecular weights for the model compounds. In such a way, the already available generalized methods can be used for calculations of the phase equilibrium in complex petroleum mixtures.
Permanent Link: http://hdl.handle.net/11104/0216314
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