Synthesis, characterization, spectroscopic and crystallographic investigation of Cobalt(III) schiff base complex with two perpendicular diamine coumarin ligands

0380114 - FZÚ 2013 RIV CN eng J - Journal Article
Ketata, I. - Mechi, L. - Ben Ayed, T. - Dušek, Michal - Petříček, Václav - Ben Hassen, R.
Synthesis, characterization, spectroscopic and crystallographic investigation of Cobalt(III) schiff base complex with two perpendicular diamine coumarin ligands.
Open Journal of Inorganic Chemistry. Roč. 2, č. 2 (2012), s. 33-39. ISSN 2161-7406
Grant - others:AV ČR(CZ) AP0701
Program: Akademická prémie - Praemium Academiae
Institutional research plan: CEZ:AV0Z10100521
Keywords : hydroxycoumarin derivative * CoIII complex * 1H NMR * UV-Visible * single crystal X-Ray diffraction
Subject RIV: BM - Solid Matter Physics ; Magnetism

New transition metal complex of Cobalt(III) of the ligand (E)-3-(1-(2-aminoethylimino)ethyl)-4-hydroxy- 2H-chromen-2-one, has been synthesized and characterized by IR, UV-Vis, 1H NMR- and 13C NMR-spectroscopy techniques. Single crystal X-ray diffraction reveled a triclinic structure consisting of isolated [Co(III)(C13H13N2O3)2]+ cations with distorted octahedral geometry, 4 counter anions, acetone solvent and water molecules. The crystal cohesion is stabilized by hydrogen bonds.
Permanent Link: http://hdl.handle.net/11104/0210913