Unveiling the topology of partially disordered micro-crystalline nitro-perylenediimide with X-aggregate stacking: an integrated approach

0585125 - FZÚ 2025 RIV GB eng J - Journal Article
Mathew, R. - Mazumder, A. - Kumar, P. - Matula, J. - Mohamed, S. - Brázda, Petr - Hariharan, M. - Thomas, B.
Unveiling the topology of partially disordered micro-crystalline nitro-perylenediimide with X-aggregate stacking: an integrated approach.
Chemical Science. Roč. 15, č. 2 (2024), s. 490-499. ISSN 2041-6520. E-ISSN 2041-6539
R&D Projects: GA ČR(CZ) GX21-05926X; GA MŠMT(CZ) EF16_019/0000760
Grant - others:OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
Research Infrastructure: CzechNanoLab - 90110; CzechNanoLab II - 90251
Institutional support: RVO:68378271
Keywords : organic molecules * nitro-perylenediimide * solid-state DMR * 3D electron diffraction
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 8.4, year: 2022
Method of publishing: Open access

Profound knowledge of the molecular structure and supramolecular organization of organic molecules is essential to understand their structure–property relationships. Herein we demonstrate the packing arrangement of partially disordered nitro-perylenediimide (NO2-PDI), revealing that the perylenediimide units exhibit an X-shaped packing pattern. The packing of NO2-PDI is derived using a complementary approach that utilises solid-state NMR (ssNMR) and 3D electron diffraction (3D ED) techniques.
Permanent Link: https://hdl.handle.net/11104/0352858