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Heterobimetallic Fe(II)-Cu(I) complexes supported with 1,1′-Bis (diphenylphosphino)ferrocene and chelating sulfur donor ligands: structural characterization, DFT analysis, anti-tyrosinase assay and biological studies
- 1.0585051 - FZÚ 2025 RIV CH eng J - Journal Article
Neshat, A. - Mahdavi, A. - Yousefshahi, M.R. - Cheraghi, M. - Mohammadi, S. - Eigner, Václav - Kučeráková, Monika - Dušek, Michal - Kaboudin, B. - Halvagar, M.R.
Heterobimetallic Fe(II)-Cu(I) complexes supported with 1,1′-Bis (diphenylphosphino)ferrocene and chelating sulfur donor ligands: structural characterization, DFT analysis, anti-tyrosinase assay and biological studies.
Journal of Organometallic Chemistry. Roč. 1005, Feb (2024), č. článku 122972. ISSN 0022-328X. E-ISSN 1872-8561
R&D Projects: GA MŠMT(CZ) EF16_019/0000760
Grant - others:OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
Institutional support: RVO:68378271
Keywords : heterobimetallic complexes * dialkyldithiophosphates * single crystal X Ray diffraction * cytotoxic * tyrosinase inhibition * density functional theory
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 2.1, year: 2023
Heterobimetallic complexes [(dppf)CuSP(S)(OiPr)2] (1), [(dppf)CuSP(S)(OEt)2] (2), [(dppf)CuSP(S)(OCy)2] (3) and [(dppf)CuS2H2B(mt)2] (4), supported with sulfur donors from the family of dialkyldithiophosphate, SP(S)(OR)2 (R = iPr, Et, Cy) and borate ligands, (S)2H2B(mt)2, were synthesized in one pot by the reaction of 1,1′-Bis(diphenylphosphino)ferrocene (dppf) with [Cu(CH3CN)4]BF4 and subsequent addition of the chelating sulfur donor ligands at room temperature in an overall moderate yield. 1-4 were characterized using a combination of 1H, 13C{1H}, 31P{1H} NMR, IR spectroscopy techniques, and single crystal X-ray diffraction.
Permanent Link: https://hdl.handle.net/11104/0352827
Number of the records: 1