Measurement system for in-situ estimation of instantaneous corrosion rate in supercritical water

0584082 - ÚFP 2024 RIV NL eng J - Journal Article
Valtr, J. - Roztočil, P. - Dašek, D. - Mušálek, Radek - Lukáč, František - Klečka, Jakub - Janata, Marek - Arnoult-Růžičková, M. - Mištová, E. - Jelínek, L. - Sajdl, P. - Macák, J.
Measurement system for in-situ estimation of instantaneous corrosion rate in supercritical water.
Journal of Supercritical Fluids. Roč. 204, January (2024), č. článku 106091. ISSN 0896-8446. E-ISSN 1872-8162
EU Projects: European Commission(BE) 945234
Institutional support: RVO:61389021
Keywords : Electrochemical Impedance Spectroscopy * High temperature corrosion * Nickel alloys * Nuclear industry * Plasmasprayed, insulation * Supercritical water
OECD category: Coating and films
Impact factor: 3.9, year: 2022
Method of publishing: Open access
https://www.sciencedirect.com/science/article/pii/S0896844623002553?via%3Dihub

Current research of cladding and in-core materials for the supercritical water reactor concept is focused on Fe-Cr-Ni alloys (e.g. 800 H, 310 S). Along the standard measurements of general corrosion rate of materials by exposure testing in autoclaves, where poor reproducibility is an issue, especially when comparing results from different experimental facilities, a good alternative may be the use of in-situ electrochemical measurements. The use of electrochemical methods is, however, more challenging due to complicated instrumentation as well as due to the supercritical water conditions. This paper is focused on the design of an experimental facility for in-situ electrochemical testing at supercritical water conditions, i.e. main circulating loop with autoclave, including the design of the electrode system, electrode leads and their surface insulation coating. Stability of electrochemical measurements has been tested using 2- and 3-electrode set-ups. Finally, surface insulation coating of the electrode leads with the best chemical and mechanical stability during experiment has been chosen for the presented application.
Permanent Link: https://hdl.handle.net/11104/0352086