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Variable temperature crystal structure of Cu.sub.4./sub.TiTe.sub.4./sub.

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    0574963 - FZÚ 2024 RIV US eng J - Journal Article
    Lakshan, A. - Petříček, Václav - Jana, P.P.
    Variable temperature crystal structure of Cu4TiTe4.
    European Journal of Inorganic Chemistry. Roč. 26, č. 24 (2023), č. článku e202300219. ISSN 1434-1948. E-ISSN 1099-0682
    Institutional support: RVO:68378271
    Keywords : atomic ordering * group-subgroup relations * phase transition * superstructures * twinning
    OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
    Impact factor: 2.3, year: 2022
    Method of publishing: Limited access
    https://doi.org/10.1002/ejic.202300219

    A variable temperature single crystal X-ray diffraction study of the ternary compound, Cu4TiTe4 is reported between 200 – 400 K. The temperature dependent study indicates the compound undergoes an order-disorder phase transition at ~320 K. Below the transition temperature, the phase that crystallizes in the primitive cubic space group, transforms into the two-fold superstructure. It is modeled as a fourfold twinned rhombohedral structure. The transition is reversible. To relate the phases, a group-subgroup symmetry relations are established.
    Permanent Link: https://hdl.handle.net/11104/0344854

     
     
Number of the records: 1  

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