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Defect pairing in Fe-doped SnS van der Waals crystals: a photoemission and scanning tunneling microscopy study

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    0574630 - FZÚ 2024 RIV GB eng J - Journal Article
    Yesilpinar, Damla - Vondráček, Martin - Čermák, P. - Mönig, H. - Kopeček, Jaromír - Caha, O. - Carva, K. - Drašar, Č. - Honolka, Jan
    Defect pairing in Fe-doped SnS van der Waals crystals: a photoemission and scanning tunneling microscopy study.
    Nanoscale. Roč. 15, č. 31 (2023), s. 13110-13119. ISSN 2040-3364. E-ISSN 2040-3372
    R&D Projects: GA MŠMT(CZ) EF16_019/0000760; GA ČR(CZ) GA22-04408S; GA ČR GA19-13659S
    Grant - others:OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
    Research Infrastructure: e-INFRA CZ II - 90254; CzechNanoLab - 90110; CzechNanoLab II - 90251
    Institutional support: RVO:68378271
    Keywords : SnS * STM * defects * magnetism * iron
    OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
    Impact factor: 6.7, year: 2022
    Method of publishing: Open access

    We investigate the effect of low concentrations of iron on the physical properties of SnS van der Waals crystals grown from the melt. By means of scanning tunneling microscopy (STM) and photoemission spectroscopy we study Fe-induced defects and observe an electron doping effect in the band structure of the native p-type SnS semiconductor. Atomically resolved and bias dependent STM data of characteristic defects are compared to ab initio density functional theory simulations of vacancy (VS and VSn), Fe substitutional (FeSn), and Fe interstitial (Feint) defects.
    Permanent Link: https://hdl.handle.net/11104/0347702

     
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