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Fine-tuning NHC ligands for ruthenium-catalyzed hydrogenation of carboxylic esters to alcohols
- 1.0574112 - ÚACH 2024 RIV NL eng J - Journal Article
Kadyrov, Renat
Fine-tuning NHC ligands for ruthenium-catalyzed hydrogenation of carboxylic esters to alcohols.
Journal of Catalysis. Roč. 426, OCT (2023), s. 173-177. ISSN 0021-9517. E-ISSN 1090-2694
Institutional support: RVO:61388980
Keywords : Alcohols * Carbene ligands * Homogeneous catalysis * Hydrogenation * Ruthenium
OECD category: Inorganic and nuclear chemistry
Impact factor: 7.3, year: 2022
Method of publishing: Limited access
https://doi.org/10.1016/j.jcat.2023.07.006
An efficient and simple catalytic system has been developed for hydrogenation of carboxylic esters. Combination of commercially available Ru-salts and simple imidazolium salts bearing N-cyclohexyl, N-cycloheptyl and N-cyclooctyl substituents enable reduction of esters to alcohols at 40 °C and 40 bar of hydrogen pressure. The reaction protocol offers a practical access to alcohols using an easy operational setup.
Permanent Link: https://hdl.handle.net/11104/0344465
Number of the records: 1