Spectroelectrochemical study on catecholase catalytic activity of selected mononuclear copper(II) complexes

0573654 - ÚFCH JH 2024 RIV GB eng J - Journal Article
Kocábová, Jana - Sýs, M. - Klikarová, J. - Novák, M. - Bártová, M. - Jirásko, R. - Tarábková, Hana - Sokolová, Romana - Mikysek, T.
Spectroelectrochemical study on catecholase catalytic activity of selected mononuclear copper(II) complexes.
Electrochimica acta. Roč. 463, SEP 2023 (2023), č. článku 142854. ISSN 0013-4686. E-ISSN 1873-3859
R&D Projects: GA ČR(CZ) GA19-03160S
Institutional support: RVO:61388955
Keywords : Mononuclear copper(II) complexes * Tyrosinase biomimetic catalyst * Catecholase-like activity
OECD category: Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Impact factor: 6.6, year: 2022
Method of publishing: Limited access

In general, a great majority of artificial enzymes provides a low substrate selectivity and negligible catalytic activity in aqueous media compared to enzymes isolated from living organisms [1]. Thus, they cannot be used as biorecognition agents in the configuration of long-life biosensors potentially applicable in clinical analysis. This problem can be solved by the synthesis of new metallo-complexes and characterization of their catalytic activity. The existence of several biomimetic sensors utilizing the artificial enzymes suggests one that this new generation of portable analytical devices will play an important role in analysis [2].
Permanent Link: https://hdl.handle.net/11104/0344044