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Grain boundary configurational entropy: a challenge

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    0573223 - FZÚ 2024 RIV DE eng J - Journal Article
    Lejček, Pavel - Školáková, Andrea
    Grain boundary configurational entropy: a challenge.
    Journal of Materials Science. Roč. 58, June (2023), s. 10043-10057. ISSN 0022-2461. E-ISSN 1573-4803
    Institutional support: RVO:68378271
    Keywords : configurational entropy * grain boundary * solute segregation * nanocrystals
    OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
    Impact factor: 4.5, year: 2022
    Method of publishing: Open access

    While the bulk of the high-entropy alloys is widely studied and characterized by their configurational entropy, there is a lack of general information regarding the configurational entropy of the grain boundaries. Here, we derived for the first time the basic relationships of this thermodynamic quantity related to the solute segregation at grain boundaries. Some examples of the appearance of the grain boundary configurational entropy are shown, and its effect on intergranular properties is discussed. It is stated that the role of grain boundary configurational entropy in interfacial properties is not completely clear and represents a challenge for future research.
    Permanent Link: https://hdl.handle.net/11104/0343690

     
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