Catching a new zeolite as a transition material during deconstruction

0571934 - FZÚ 2024 RIV US eng J - Journal Article
Yue, Q.D. - Steciuk, Gwladys - Mazur, M. - Zhang, J. - Petrov, O. - Shamzhy, M. - Liu, M. - Palatinus, Lukáš - Čejka, J. - Opanasenko, M.
Catching a new zeolite as a transition material during deconstruction.
Journal of the American Chemical Society. Roč. 145, č. 16 (2023), s. 9081-9091. ISSN 0002-7863. E-ISSN 1520-5126
R&D Projects: GA ČR GA19-08032S; GA MŠMT(CZ) EF16_019/0000760; GA MŠMT LM2018110
Grant - others:OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
Research Infrastructure: e-INFRA CZ - 90140
Institutional support: RVO:68378271
Keywords : crystal structure * crystal * layers * materials * zeolites
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 15, year: 2022
Method of publishing: Open access

Zeolites are key materials in both basic research and industrial applications. However, their synthesis is neither diverse nor applicable to labile frameworks because classical procedures require harsh hydrothermal conditions, whereas post-synthesis methods are limited to a few suitable parent materials. Remaining frameworks can fail due to amorphization, dissolution, and other decomposition processes. Nevertheless, stopping degradation at intermediate structures could yield new zeolites. Here, by optimizing the design and synthesis parameters of the parent zeolite IWV, we we ‚‚caught‘‘ a new, highly crystalline, and siliceous zeolite during its degradation.
Permanent Link: https://hdl.handle.net/11104/0342831