Study of the one-step in situ growth synthesis of Cu-Pic coordination polymer and Cu-BTC MOF and their performances for detection of 4-Nitrophenol

0570388 - FZÚ 2024 RIV US eng J - Journal Article
Shahbakhsh, M. - Saravani, H. - Dušek, Michal - Poupon, Morgane
Study of the one-step in situ growth synthesis of Cu-Pic coordination polymer and Cu-BTC MOF and their performances for detection of 4-Nitrophenol.
Microchemical Journal. Roč. 189, June (2023), č. článku 108557. ISSN 0026-265X. E-ISSN 1095-9149
R&D Projects: GA MŠMT LM2018110
Institutional support: RVO:68378271
Keywords : in situ growth strategy * metal-organic framework * Cu-Pic CP * Cu-BTC MOF * 4-nitrophenol * electrochemical sensor
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 4.8, year: 2022
Method of publishing: Limited access
https://doi.org/10.1016/j.microc.2023.108557

Herein we report the one-step in situ growth of Cu-Pic coordination polymer (Cu-Pic CP) and Cu-BTC metal–organic framework (MOF) for the first time. The oxidation of copper substrate to Cu2+ ions and their reaction with the organic ligands is performed simultaneously. Then the grown crystals can be easily removed from the surface by shaking. Both compounds are characterized using single crystal (SXRD) and (PXRD) X-ray diffraction analysis, infrared analysis (FTIR), energy dispersive X-ray analysis (EDX), field emission electron microscopy (ESEM), Brunauer-Emmett-Teller (BET) surface area analys is, and the thermal gravimetric analysis (TGA).
Permanent Link: https://hdl.handle.net/11104/0341703