Template synthesis, characterization and antibacterial activity of d.sup.10./sup. (Zn.sup.2+./sup., Cd.sup.2+./sup., Hg.sup.2+./sup.) Schiff base complexes: a novel supramolecular Cd.sup.2+./sup. complex with two 1D helical chains, and its Hirshfeld surface analysis

0566219 - FZÚ 2024 RIV NL eng J - Journal Article
Tyula, Y.A. - Goudarziafshar, H. - Yousefi, S. - Dušek, Michal - Eigner, Václav
Template synthesis, characterization and antibacterial activity of d¹⁰ (Zn²⁺, Cd²⁺, Hg²⁺) Schiff base complexes: a novel supramolecular Cd²⁺ complex with two 1D helical chains, and its Hirshfeld surface analysis.
Journal of Molecular Structure. Roč. 1272, Jan (2023), č. článku 134051. ISSN 0022-2860. E-ISSN 1872-8014
R&D Projects: GA ČR(CZ) GA14-03276S
Institutional support: RVO:68378271
Keywords : Schiff base complex * Hirshfeld analysis * antibacterial activity * 5-Bromo salicylaldehyde * single crystal X-ray crystallography
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 3.8, year: 2022
Method of publishing: Limited access
https://doi.org/10.1016/j.molstruc.2022.134051

Three new macroacyclic Schiff base complexes were prepared via condensation of N,N,N',N'-tetrakis(2-aminoethyl) ethylenediamine hydrobromide with 5-bromo salicylaldehyde in the presence of metal ions (Zn2+, Cd2+, Hg2+) as template agents. The compounds were studied with elemental analysis, FT-IR, and 1H, 13C NMR spectroscopy. The structure of the Cd(II) complex, Cd(H2L)].2H2O, (H4L = N,N,N',N'-tetrakis(5-bromo salicylidene) N,N,N',N'-tetrakis(2-aminoethyl) ethylenediamine), was determined by single crystal X-ray crystallography.
Permanent Link: https://hdl.handle.net/11104/0341678