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Fluoroalkyl Azides and Triazoles: Unlocking a Novel Chemical Space
- 1.0565754 - ÚOCHB 2023 RIV US eng J - Journal Article
Markos, Athanasios - Matoušek, V. - Beier, Petr
Fluoroalkyl Azides and Triazoles: Unlocking a Novel Chemical Space.
Aldrichimica Acta. Roč. 55, č. 2 (2022), s. 37-44. ISSN 0002-5100
Institutional support: RVO:61388963
Keywords : nitrogen heterocycles * azides * triazoles * cycloaddition * rhodium catalysis * copper catalysis * carbenes * enamides * imidoyl halides
OECD category: Organic chemistry
Impact factor: 3.6, year: 2022
Method of publishing: Open access
https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/232/066/acta55-point-1-and-2-2022-br9200en-mk.pdf#page=43
Fluorinated azidoalkanes have emerged recently as novel and surprisingly stable azides. Their easy preparation and commercial availability have opened up new possibilities for their application in organic synthesis. This review is focused on the use of fluorinated azidoalkanes in cycloaddition reactions leading to N-fluoroalkyl-1,2,3-triazoles. It also covers the rhodiumcatalyzed and acid-mediated transformations of the triazoles to afford a variety of new N-fluoroalkyl nitrogen heterocycles and N-alkenyl compounds.
Permanent Link: https://hdl.handle.net/11104/0337263
Number of the records: 1