Black phosphorus: Fundamental properties and influence of impurities induced by its synthesis

0563848 - FZÚ 2023 RIV US eng J - Journal Article
Antonatos, N. - Šturala, J. - Mazánek, V. - Sedmidubský, D. - Veselý, M. - Růžička, K. - Hejtmánek, Jiří - Levinský, Petr - Sofer, Z.
Black phosphorus: Fundamental properties and influence of impurities induced by its synthesis.
ACS Applied Materials and Interfaces. Roč. 14, č. 30 (2022), s. 34867-34874. ISSN 1944-8244. E-ISSN 1944-8252
R&D Projects: GA ČR GA18-12761S; GA MŠMT(CZ) LM2018096
Institutional support: RVO:68378271
Keywords : phosphorene * black phosphorus * high-pressure synthesis * transport properties * ceramic * nanostructures
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 9.5, year: 2022
Method of publishing: Limited access
https://doi.org/10.1021/acsami.2c08714

Black phosphorus (BP) has been among the most widely explored materials in recent years because of its exceptional properties. A vapor transport method using tin and iodide as mineralizers was used to synthesize large crystals which can be used for fundamental physical characterization including electrical and heat transport and heat capacity. This method is compared to other reported procedures (high-pressure crystal growth and mercury catalysis) which are broadly used and the most dominant procedures for the obtainment of bulk layered BP. In addition, we have investigated any possible impurities which could have been introduced by synthesis and their possible incorporation into BP and their influence on the physical properties of BP.
Permanent Link: https://hdl.handle.net/11104/0335636