A new heterotrimetallic sandwich-like Cu.sup.II./sup.-La.sup.III./sup.-Cu.sup.II./sup. (3d-4f-3d) cluster as a model anticancer drug in interaction with FS-DNA and BSA and as a new artificial catalyst for catecholase activity

0562294 - FZÚ 2023 RIV GB eng J - Journal Article
Keshavarzian, E. - Asadi, Z. - Poupon, Morgane - Dušek, Michal - Rastegari, B.
A new heterotrimetallic sandwich-like Cu^II-La^III-Cu^II (3d-4f-3d) cluster as a model anticancer drug in interaction with FS-DNA and BSA and as a new artificial catalyst for catecholase activity.
Applied Organometallic Chemistry. Roč. 36, č. 11 (2022), č. článku e6856. ISSN 0268-2605. E-ISSN 1099-0739
R&D Projects: GA MŠMT(CZ) EF16_019/0000760
Grant - others:OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
Institutional support: RVO:68378271
Keywords : catecholase activity * DNA and BSA binding * heterotrimetallic Cu–La–Cu cluster * MTT assay
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 3.9, year: 2022
Method of publishing: Limited access
https://doi.org/10.1002/aoc.6856

A new heterotrimetallic sandwich-like CuII–LaIII–CuII cluster, [(valpn)2Cu2La(NO3)2]NO3(H2O)1.8, (H2valpn = 1,3-propanediylbis(2-iminomethylene-6-methoxy-phenol)), was synthesized by the reaction of [Cu(valpn)] with La(NO3)3.6H2O (1:1 M ratio) at room temperature. The resulted cluster was characterized by X-ray diffraction, UV–Vis and IR spectroscopy, and elemental analysis (CHN).
Permanent Link: https://hdl.handle.net/11104/0334640