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Temperature-induced charge transfer in Fe-doped ZnSe single crystal: mechanism and features

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    0562087 - FZÚ 2023 RIV DE eng J - Journal Article
    Lamonova, K. - Orel, S. - Pashkevich, Y. - Bekirov, B. - Hidulianov, M. - Ivanchenko, I. - Popenko, N. - Kovalenko, N. - Prokhorov, Andriy - Hizhnyi, Yu. - Nedilko, S. - Klyui, N.
    Temperature-induced charge transfer in Fe-doped ZnSe single crystal: mechanism and features.
    European Physical Journal Plus. Roč. 137, č. 9 (2022), č. článku 1018. ISSN 2190-5444. E-ISSN 2190-5444
    R&D Projects: GA MŠMT(CZ) EF16_019/0000760; GA ČR(CZ) GA20-21069S
    Grant - others:OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
    Institutional support: RVO:68378271
    Keywords : electron-paramagnetic-resonance * transition * spectroscopy * spintronics * dynamics * state * ion
    OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
    Impact factor: 3.4, year: 2022
    Method of publishing: Limited access
    https://doi.org/10.1140/epjp/s13360-022-03237-x

    We have collected the EPR spectra for Fe ions of zinc selenide single crystals in the temperature range from 5 to 300 K. The samples under test were grown by the Bridgman method and had a homogeneous structure of the ZnSe:Fe solid solution. Temperature-induced charge transfer from Fe3+ into Fe2+ on cooling is detected. The EPR spectrum formationmechanism is studied using a complex theoretical approach that combines the semi-empirical Modified Crystal Field Theory and structure optimizations using the DFT-based band-periodic plane-wave pseudopotential method.
    Permanent Link: https://hdl.handle.net/11104/0334507

     
     
Number of the records: 1  

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