EPR/UV-VIS-NIR Spectroelectrochemical Examination of the Association Properties of Thienoacene-Bridged Tetrathiafulvalenes Supported by DFT Calculations

0549330 - ÚFCH JH 2024 RIV CZ eng C - Conference Paper (international conference)
Lušpai, Karol - Rapta, P. - Zalibera, M. - Darvasiová, D. - Lukeš, V.
EPR/UV-VIS-NIR Spectroelectrochemical Examination of the Association Properties of Thienoacene-Bridged Tetrathiafulvalenes Supported by DFT Calculations.
Sborník přednášek mezinárodní odborné konference XL. Moderní Elektrochemické Metody. Ústí nad Labem: Best Servis, 2021 - (Navrátil, T.; Fojta, M.; Schwarzová, K.), s. 151-154. ISBN 978-80-905221-8-3.
[Moderní Elektrochemické Metody /40./. Jetřichovice (CZ), 08.11.2021-12.11.2021]
Institutional support: RVO:61388955
Keywords : Tetrathiafulvalene * EPR/UV-VIS-NIR spectroelectrochemistry * Cyclic voltammetry
OECD category: Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

This work was focused on the EPR/UV-VIS-NIR spectroelectrochemical examination of
association properties of radical cations electrochemically produced from tetrathiafulvalene
(TTF) derivatives, in relation to the molecular structure, mainly the number and orientation of
thiophene rings in the spacer between fulvalene redox centers. Results from EPR/UV-VIS-NIR
spectroelectrochemistry were supported by DFT calculations.
Permanent Link: http://hdl.handle.net/11104/0325347