Osmium and lithium isotope evidence for weathering feedbacks linked to orbitally paced organic carbon burial and Silurian glaciations

0547736 - GLÚ 2022 RIV NL eng J - Journal Article
Sproson, A. D. - Pogge Von Strandmann, P. A. E. - Selby, D. - Jarochowska, E. - Frýda, J. - Hladil, Jindřich - Loydell, D. K. - Slavík, Ladislav - Calner, M. - Maier, G. - Munnecke, A. - Lenton, T. M.
Osmium and lithium isotope evidence for weathering feedbacks linked to orbitally paced organic carbon burial and Silurian glaciations.
Earth and Planetary Science Letters. Roč. 577, January 2022 (2022), č. článku 117260. ISSN 0012-821X. E-ISSN 1385-013X
R&D Projects: GA ČR(CZ) GA17-06700S
Institutional support: RVO:67985831
Keywords : osmium (¹⁸⁷Os/¹⁸⁸Os) and lithium (δ⁷Li) * isotopes * Silurian palaeoclimate * Hirnantian glaciation * orbital obliquity * eccentricity and precession * silicate weathering
OECD category: 1.5. Earth and related environmental sciences
Impact factor: 5.3, year: 2022
Method of publishing: Limited access
https://www.sciencedirect.com/science/article/pii/S0012821X21005161?via%3Dihub#!

The Ordovician (∼487 to 443 Ma) ended with the formation of extensive Southern Hemisphere ice sheets, known as the Hirnantian glaciation, and the second largest mass extinction in Earth History. It was followed by the Silurian (∼443 to 419 Ma), one of the most climatically unstable periods of the Phanerozoic as evidenced by several large scale (> 5‰) carbon isotope (δ¹³C) perturbations associated with further extinction events. Despite several decades of research, the cause of these environmental instabilities remains enigmatic. Here, we provide osmium (¹⁸⁷Os/¹⁸⁸Os) and lithium (δ⁷Li) isotope measurements of marine sedimentary rocks that cover four Silurian δ¹³C excursions. Osmium and Li isotope records resemble those previously recorded for the Hirnantian glaciation suggesting a similar causal mechanism. When combined with a new dynamic carbon-osmium-lithium biogeochemical model we suggest that astronomical forcing of the marine organic carbon cycle, as opposed to a decline in volcanic arc degassing or the rise of early land plants, resulted in drawdown of atmospheric CO₂, triggering continental scale glaciation, intense global cooling and eustatic sea-level lows recognised in the geological record. Lower atmospheric pCO₂ and temperatures during the Hirnantian and Silurian glaciations suppressed CO₂ removal by silicate weathering, driving ¹⁸⁷Os/¹⁸⁸Os and δ⁷Li variability, supporting the existence of climate-regulating feedbacks.
Permanent Link: http://hdl.handle.net/11104/0326899