Quantification of pedogenic particles masked by geogenic magnetic fraction

0543934 - GFÚ 2022 RIV GB eng J - Journal Article
Szuszkiewicz, M. - Grison, Hana - Petrovský, Eduard - Szuszkiewicz, M. M. - Goluchowska, B. - Lukasik, A.
Quantification of pedogenic particles masked by geogenic magnetic fraction.
Scientific Reports. Roč. 11, č. 1 (2021), č. článku 14800. ISSN 2045-2322. E-ISSN 2045-2322
R&D Projects: GA MŠMT(CZ) LTV19011; GA MŠMT(CZ) LTC19029
Institutional support: RVO:67985530
Keywords : environmental magnetism * soils * pedogenesis * lithology * iron oxides * geochemistry
OECD category: 1.7 Other natural sciences
Impact factor: 4.997, year: 2021
Method of publishing: Open access
https://www.nature.com/articles/s41598-021-94039-1

Pedogenic magnetic fraction in soils is attributed to fine-grained particles, i.e. superparamagnetic grains. In the case of a strongly magnetic geogenic fraction, pedogenic magnetic contribution is hard to detect. To the best of our knowledge, detailed research into the masking of pedogenic superparamagnetic grains and quantification of this effect has not yet been carried out. The principal aim of our research is to quantify the influence of coarse-grained ferrimagnetic fraction on the detection of the superparamagnetic grains. In order to describe the masking phenomenon, volume and frequency-dependent magnetic susceptibility were determined on a set of laboratory prepared samples composed of natural substances: a diamagnetic quartz matrix, detrital coarse-grained ferrimagnetic crystals from alkaline and ultra-alkaline igneous rocks, and superparamagnetic soil concretions formed in the Haplic Cambisol. Mineralogy, concentration, type and grain size of the tested material were described by parameters of environmental magnetism. The magnetic parameters distinguish both geogenic multidomain and pedogenic superparamagnetic grains. The magnetic signal of the superparamagnetic grains is gradually masked by the increasing proportion of multidomain grains of magnetite/maghemite. The experiment clearly describes the masking effect and brings new insight to studies dealing with strongly magnetic soils of natural and/or highly contaminated origin as a tool for estimation of superparamagnetic pedogenic contribution.
Permanent Link: http://hdl.handle.net/11104/0321029