Residual- and linker-free metal/polymer nanofluids prepared by direct deposition of magnetron-sputtered Cu nanoparticles into liquid PEG

0542951 - FZÚ 2022 RIV NL eng J - Journal Article
Choukourov, A. - Nikitin, D. - Pleskunov, P. - Tafiichuk, R. - Biliak, K. - Protsak, M. - Kishenina, K. - Hanuš, J. - Dopita, M. - Cieslar, M. - Popelář, Tomáš - Ondič, Lukáš - Varga, Marián
Residual- and linker-free metal/polymer nanofluids prepared by direct deposition of magnetron-sputtered Cu nanoparticles into liquid PEG.
Journal of Molecular Liquids. Roč. 336, Aug (2021), č. článku 116319. ISSN 0167-7322. E-ISSN 1873-3166
Institutional support: RVO:68378271
Keywords : nanofluid * magnetron sputtering * gas aggregation cluster source * copper nanoparticles * polyethylene glycol
OECD category: Fluids and plasma physics (including surface physics)
Impact factor: 6.633, year: 2021
Method of publishing: Limited access
https://doi.org/10.1016/j.molliq.2021.116319

Colloidal solutions of metal nanoparticles (NPs) are typically produced by multi-step methods using a variety of chemicals. Resultant nanofluids require extra purification steps to remove the reactions byproducts and modification steps to introduce anticoagulants for the solution stabilization. Here, we suggest a single-step method to produce nanofluid in which only two components are present: 22 nm-sized Cu NPs as a filler and polyethylene glycol (PEG, 400 g/mol) as a liquid base. The method employs magnetron sputtering to synthesize Cu NPs in a gas aggregation cluster source and their subsequent loading into vacuum-compatible PEG. The resultant nanofluid demonstrates strong plasmonic and photoluminescent activity, and shows enhanced stability over time, in contrast to conventional colloidal solutions. The approach offers an alternative for the production of nanofluids in which the processes of the NP formation are decoupled from the processes of their mixing with the liquid base.
Permanent Link: http://hdl.handle.net/11104/0320275