Dioxygen splitting at room temperature over distant binuclear transition metal centers in zeolites for direct oxidation of methane to methanol

0541903 - ÚFCH JH 2022 RIV GB eng J - Journal Article
Mlekodaj, Kinga - Lemishka, Mariia - Sklenák, Štěpán - Dědeček, Jiří - Tabor, Edyta
Dioxygen splitting at room temperature over distant binuclear transition metal centers in zeolites for direct oxidation of methane to methanol.
Chemical Communications. Roč. 57, č. 28 (2021), s. 3472-3475. ISSN 1359-7345. E-ISSN 1364-548X
R&D Projects: GA ČR(CZ) GA17-00742S; GA ČR(CZ) GA19-02901S
Institutional support: RVO:61388955
Keywords : zeolites * oxidation * methane * methanol
OECD category: Physical chemistry
Impact factor: 6.065, year: 2021
Method of publishing: Limited access

Here we demonstrate for the first time the splitting of dioxygen at RT over distant binuclear transition metal (M = Ni, Mn, and Co) centers stabilized in ferrierite zeolite. Cleaved dioxygen directly oxidized methane to methanol, which can be released without the aid of an effluent to the gas phase at RT.
Permanent Link: http://hdl.handle.net/11104/0319400