Iron(III) and cobalt(III) complexes with pentadentate pyridoxal Schiff base ligand - structure, spectral, electrochemical, magnetic properties and DFT calculations

0541755 - FZÚ 2022 RIV GB eng J - Journal Article
Murašková, V. - Eigner, Václav - Dušek, Michal - Sedmidubský, D.
Iron(III) and cobalt(III) complexes with pentadentate pyridoxal Schiff base ligand - structure, spectral, electrochemical, magnetic properties and DFT calculations.
Polyhedron. Roč. 197, Mar (2021), č. článku 115019. ISSN 0277-5387. E-ISSN 1873-3719
R&D Projects: GA MŠMT LM2018110
Research Infrastructure: e-INFRA CZ - 90140
Institutional support: RVO:68378271
Keywords : iron(III) complex * cobalt(III) complex * pyridoxal * pentadentate Schiff base * crystal structure * magnetic properties * cyclic voltammetry * DFT calculations
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 2.975, year: 2021
Method of publishing: Limited access
https://doi.org/10.1016/j.poly.2021.115019

Three complexes, [FeLCl]Cl.H2O, [Co2L2H3O2]Cl.4.8H2O, and [CoLN3], where L2– is the dianion of an asymmetric propyl-ethyl pentadentate Schiff base ligand condensed from pyridoxal and N-(2-aminoethyl)propane-1,3-diamine, have been synthesized and characterized by elemental analysis, FT-IR and mass spectroscopy. Crystal structures of the complexes along with the Schiff base were determined by X-ray diffraction. 1HNMR spectrum of the Schiff base has been obtained.
Permanent Link: http://hdl.handle.net/11104/0319285