Number of the records: 1
Synthesis of N-perfluoroalkyl-3,4-disubstituted pyrroles by rhodium-catalyzed transannulation of N-fluoroalkyl-1,2,3-triazoles with terminal alkynes
- 1.0541477 - ÚOCHB 2022 RIV DE eng J - Journal Article
Bakhanovich, Olga - Khutorianskyi, Viktor V. - Motornov, Vladimir - Beier, Petr
Synthesis of N-perfluoroalkyl-3,4-disubstituted pyrroles by rhodium-catalyzed transannulation of N-fluoroalkyl-1,2,3-triazoles with terminal alkynes.
Beilstein Journal of Organic Chemistry. Roč. 17, Feb 18 (2021), s. 504-509. ISSN 1860-5397. E-ISSN 1860-5397
R&D Projects: GA MŠMT LTAUSA18037
Institutional support: RVO:61388963
Keywords : pyrrole * transannulation * rhodium carbene * triazole
OECD category: Organic chemistry
Impact factor: 2.544, year: 2021
Method of publishing: Open access
https://doi.org/10.3762/bjoc.17.44
The rhodium-catalyzed transannulation of N-perfluoroalkyl-1,2,3-triazoles with aromatic and aliphatic terminal alkynes under microwave heating conditions afforded N-perfluoroalkyl-3,4-disubstituted pyrroles (major products) and N-fluoroalkyl-2,4-disubstituted pyrroles (minor products). The observed selectivities in the case of the reactions with aliphatic alkynes were high.
Permanent Link: http://hdl.handle.net/11104/0319028
Number of the records: 1