Formation of graphene oxide-based ordered structures in epoxy: effect of grafted polymer chains

0541328 - ÚMCH 2022 RIV US eng J - Journal Article
Kelnar, Ivan - Kaprálková, Ludmila - Krejčíková, Sabina - Zhigunov, Alexander - Dybal, Jiří - Pavlovec, Lukáš - Janata, Miroslav
Formation of graphene oxide-based ordered structures in epoxy: effect of grafted polymer chains.
Polymer-Plastics Technology and Materials. Roč. 60, č. 10 (2021), s. 1084-1097. ISSN 2574-0881. E-ISSN 2574-089X
R&D Projects: GA ČR(CZ) GA19-06065S
Institutional support: RVO:61389013
Keywords : epoxy nanocomposites * mechanical properties * microstructure
OECD category: Composites (including laminates, reinforced plastics, cermets, combined natural and synthetic fibre fabrics
Impact factor: 2.439, year: 2021
Method of publishing: Limited access
https://www.tandfonline.com/doi/full/10.1080/25740881.2021.1876882

Graphene oxide (GO) has high potential for grafting of polymer chains. This mostly enhances exfoliation or controls structure-directing effects in thermoplastic blends, whereas various complex arrays may be formed in the case of epoxy thermosets. This study reveals that the structure of these arrays is markedly influenced by parameters of grafted polymer chains and geometry of grafting. The best-balanced properties were found for nacre-mimicking lamellar arrays with an important role of internal structure and elasticity of grafted chains. Beneficial is s relatively thick “elastic interlayer” of grafted butadiene‐acrylonitrile copolymer with toughening effect comparable to much higher content of free polymer addition.
Permanent Link: http://hdl.handle.net/11104/0319043