Number of the records: 1
Stuffed pumpkins: mechanochemical synthesis of host-guest complexes with cucurbit[7]uril
- 1.0541260 - ÚOCHB 2022 RIV GB eng J - Journal Article
Dračínský, Martin - Santos Hurtado, Carina - Masson, E. - Kaleta, Jiří
Stuffed pumpkins: mechanochemical synthesis of host-guest complexes with cucurbit[7]uril.
Chemical Communications. Roč. 57, č. 17 (2021), s. 2132-2135. ISSN 1359-7345. E-ISSN 1364-548X
R&D Projects: GA ČR(CZ) GA20-13745S; GA ČR(CZ) GA20-01472S; GA MŠMT(CZ) LTAUSA19120
Institutional support: RVO:61388963
Keywords : mechanochemical synthesis * macrocyles * host-guest complexes * cucurbit[7]uril
OECD category: Organic chemistry
Impact factor: 6.065, year: 2021
Method of publishing: Limited access
https://doi.org/10.1039/D1CC00240F
Solvent-free mechanochemical synthesis (ball-milling) was used to prepare inclusion complexes with cucurbit[7]uril and four model guest molecules (adamantane, adamantyl-1-amine hydrochloride, toluidine hydrochloride, and p-phenylenediamine dihydrochloride). Successful formation of individual inclusions was independently confirmed by one- and two-dimensional solid-state NMR techniques and differential scanning calorimetry. Mechanochemical synthesis represents an alternative path towards new types of cucurbit[n]uriliguest inclusion complexes that are not accessible due to limited solubility of the individual components.
Permanent Link: http://hdl.handle.net/11104/0318850
Number of the records: 1