Synthesis, characterization, and crystal structures of a thiosemicarbazone ligand and its silver(I) complex

0535342 - FZÚ 2021 RIV IR eng J - Journal Article
Khalaji, A.D. - Shahsavani, E. - Dušek, Michal - Kučeráková, Monika - Eigner, Václav
Synthesis, characterization, and crystal structures of a thiosemicarbazone ligand and its silver(I) complex.
Iranian Journal of Chemistry & Chemical Engineering-International English Edition. Roč. 39, č. 4 (2020), s. 23-28. ISSN 1021-9986. E-ISSN 1021-9986
R&D Projects: GA MŠMT(CZ) LO1603; GA ČR GA15-12719S
EU Projects: European Commission(CZ) CZ.2.16/3.1.00/24510
Institutional support: RVO:68378271
Keywords : thiosemicarbazone * silver(I) complex * single crystal * triclinic structure * tetrahedral coordination
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 0.759, year: 2020
Method of publishing: Open access

Thiosemicarbazone ligand 4Hbatsc = 4-hydroxybenzaldehyde-thiosemicarbazone and its silver(I) complex [Ag(PPh3)3(4Hbatsc)]NO3 were synthesized and characterized by elemental analysis (CHN), FT-IR spectroscopy, and single-crystal X-ray diffraction. Besides, the thermal behavior of the complex was studied using thermogravimetry in order to evaluate its thermal stability and thermal decomposition pathway. Finally, nanoparticles of the complex were prepared in an ultrasonic bath.

Permanent Link: http://hdl.handle.net/11104/0313391