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Selected ion flow tube mass spectrometry analyses of isobaric compounds methanol and hydrazine in humid air

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    0531422 - ÚFCH JH 2021 RIV GB eng J - Journal Article
    Shestivska, Violetta - Kolivoška, Viliam - Kubišta, Jiří - Smith, D. - Španěl, Patrik
    Selected ion flow tube mass spectrometry analyses of isobaric compounds methanol and hydrazine in humid air.
    Rapid Communications in Mass Spectrometry. Roč. 34, č. 10 (2020), č. článku e8744. ISSN 0951-4198. E-ISSN 1097-0231
    R&D Projects: GA ČR(CZ) GA18-09848S
    Institutional support: RVO:61388955
    Keywords : trace gas-analysis * sift-ms * breath * mechanisms * kinetics * o-2(+) * h3o+ * co2
    OECD category: Physical chemistry
    Impact factor: 2.419, year: 2020
    Method of publishing: Limited access

    Rationale The volatile compounds generated by the electrochemical reduction of atmospheric carbon dioxide and nitrogen include isobaric methanol (CH3OH) and, potentially, hydrazine (N2H4). To achieve quantification of hydrazine molecules by selected ion flow tube mass spectrometry (SIFT-MS), its reactions with H3O+, NO+ and O-2(+) reagent ions must be understood.
    Permanent Link: http://hdl.handle.net/11104/0310086

     
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