Comparison of prediction methods of heat capacity of ionic liquids with selected experimental data by means of advanced data analysis.

0524600 - ÚCHP 2021 RIV NL eng J - Journal Article
Čanji, Maja - Bendová, Magdalena - Wagner, Zdeněk
Comparison of prediction methods of heat capacity of ionic liquids with selected experimental data by means of advanced data analysis.
Thermochimica Acta. Roč. 690, 20 AUG (2020), č. článku 178602. ISSN 0040-6031. E-ISSN 1872-762X
R&D Projects: GA ČR(CZ) GA17-08218S
Institutional support: RVO:67985858
Keywords : ionic liquids * isobaric heat capacity * differential scanning calorimetry
OECD category: Physical chemistry
Impact factor: 3.115, year: 2020
Method of publishing: Open access with time embargo

Heat capacity of selected series of ionic liquids was predicted by means of several group contribution models of ionic liquid and compared with available experimental data. The examined series of ionic liquids were with methylimidazolium, menthoxymethyl imidazolium and ethoxyethoxyethyl imidazolium cations with different alkyl substituents, while the anions were the saccharinate or bistriflate. All data, experimental and predicted, were analyzed by means of mathematical gnostics and critically evaluated. Based on the thermodynamics of data and theory of measurement, mathematical gnostics is a novel non-statistical approach towards data uncertainty.
Permanent Link: http://hdl.handle.net/11104/0310661