Preparation of ultrafine fibrous uranium dioxide by electrospinning

0519171 - ÚPT 2021 RIV NL eng J - Journal Article
Kundrát, V. - Paták, Aleš - Pinkas, J.
Preparation of ultrafine fibrous uranium dioxide by electrospinning.
Journal of Nuclear Materials. Roč. 528, JAN (2020), č. článku 151877. ISSN 0022-3115. E-ISSN 1873-4820
Institutional support: RVO:68081731
Keywords : electrospinning * uranyl * oxide * nanofibers * aluminum foil * polyvinylpyrrolidone
OECD category: Inorganic and nuclear chemistry
Impact factor: 2.936, year: 2020
Method of publishing: Limited access
https://www.sciencedirect.com/science/article/abs/pii/S0022311519309997

We are introducing for the first time a robust method for the preparation of uranium oxide nanofibers with extraordinary thin diameters. We have studied the preparation of U3O8 and UO2 nanofibers by the electrospinning method from uranyl acetylacetonate in mixed organic solvents. Polyvinylpyrrolidone (PVP) was used as a supporting polymer. Besides studying and optimizing the solution systems, we have also examined the effects of collector material on the properties of the fiber mat. We have found that calcination of electrospun green composite fibers deposited on aluminum foil produces U3O8 nanofibers with the lowest average diameter of 20 +/- 5 nm as their adhesion prevents fiber shrinking. We have also studied calcination of fibers on ashless paper and freestanding composite mats. Reduction of U3O8 fibers in H-2/N-2 atmosphere at various temperatures provided uranium dioxide nanofibers with an average diameter of 90 nm. (C) 2019 Elsevier B.V. All rights reserved.
Permanent Link: http://hdl.handle.net/11104/0304195