Sonochemical synthesis and characterization of nano-sized copper(I) thiosemicarbazone complex: crystal structure and thermal study

0519071 - FZÚ 2020 RIV IR eng J - Journal Article
Khalaji, A.D. - Shahsavani, E. - Dušek, Michal - Kučeráková, Monika
Sonochemical synthesis and characterization of nano-sized copper(I) thiosemicarbazone complex: crystal structure and thermal study.
Journal of the Iranian Chemical Society. Roč. 16, č. 6 (2019), s. 1179-1187. ISSN 1735-207X. E-ISSN 1735-2428
R&D Projects: GA MŠMT(CZ) LO1603; GA ČR(CZ) GA18-10504S
EU Projects: European Commission(CZ) CZ.2.16/3.1.00/24510
Institutional support: RVO:68378271
Keywords : nano-sized copper(I) complex * thiosemicarbazone * ultrasonic bath * spectroscopy * crystal structure * XRD * SEM
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 1.552, year: 2019
Method of publishing: Limited access
https://doi.org/10.1007/s13738-019-01592-8

In this work, we report the synthesis, characterization, crystal structure, and thermal and antibacterial studies of a new nano-sized copper(I) thiosemicarbazone complex prepared by an ultrasonic bath assisted synthesis in an acetonitrile solution. Characterization of the complex and its ligand (EHB-tsc = 3-ethoxy--hydroxybenzaldehyde-thiosemicarbazone) was performed using elemental analysis, FT-IR, 1H and 13C-NMR, UV–Vis spectroscopy, thermal gravimetry, and singlecrystal X-ray diffraction. In addition, the complex was characterized by X-ray powder diffraction and scanning electron microscopy.
Permanent Link: http://hdl.handle.net/11104/0304091