ZEOLITES IN CATALYSIS: PROPERTIES AND APPLICATIONS

0506751 - ÚFCH JH 2020 RIV GB eng M - Monography Chapter
Opanasenko, Maksym
Zeolites for Fine Chemistry.
RSC Catalysis Series. In: ZEOLITES IN CATALYSIS: PROPERTIES AND APPLICATIONS. Vol. 28. Cambs: ROYAL SOC CHEMISTRY, 2017 - (Čejka, J.; Morris, R.; Nachtigall, P.), Roč. 28 (2017), s. 409-440. ISBN 978-1-78262-784-5
Institutional support: RVO:61388955
Keywords : meerwein-ponndorf-verley * baeyer-villiger oxidation * friedel-crafts acylation * sn-beta zeolite * shape-selective catalysis * diels-alder cycloaddition * large-pore zeolites * acetic-anhydride * oppenauer reactions * titanium beta
OECD category: Physical chemistry

High stability, predictable behavior, and possibility to vary catalytic parameters of conventional zeolites determine their importance for application in fine chemistry. In this chapter, zeolite-assisted acid-catalysed and redox reactions resulting in the production of fragrances, drugs, and other valuable small-scale products are discussed. Fundamental aspects and key factors influencing the catalytic activity of zeolites are considered, including characteristics such as topology of the framework, type and number of the active sites, nature of framework atoms, hydrophilicity, etc. Application of zeolites in aromatic substitution, isomerization, hydroxyalkylation, epoxidation, and other industrially important reactions is highlighted.


Permanent Link: http://hdl.handle.net/11104/0297932