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Photochemical Derivatization of Helicenes.

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    0497000 - ÚCHP 2019 CZ eng C - Conference Paper (international conference)
    Jakubec, Martin - Ghosh, I. - Storch, Jan - König, B.
    Photochemical Derivatization of Helicenes.
    Book of Abstracts. Louvain-la-Neuve: Université catholique de Louvain, 2018 - (Gaigneux, E.), s. 85, č. článku P 21. ISBN N.
    [Advances in Organic, Bioorganic and Pharmaceutical Chemistry LIBLICE 2018 /53./. Lázně Bělohrad (CZ), 02.11.2018-04.11.2018]
    R&D Projects: GA MPO FV10082
    Institutional support: RVO:67985858
    Keywords : helicene * photochemistry * substrates
    OECD category: Organic chemistry

    This work is focused on the use of simple helicene derivatives as substrates for modern photochemical methods. Halogen containing substrates are transformed in the reductive pathway to helicenyl radicals, before being trapped by different radical traps. In the oxidative pathway, activated alkoxyhelicenes undergo photoredox catalyzed reactions, yielding various carbon-carbon, as well as carbon-heteroatom containing compounds.

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    SKMBT_C22018110615051.pdf21360.8 KBPublisher’s postprintopen-access
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